Foods and Raw Materials, 2014, том 2, № 2
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КемТИПП ISSN 2308-4057 FOODS AND DAW MATEDIALS Vol.2 (№212014
The Ministry of Education and ISSN 2308-4057 (Print) Science of the Russian Federation ISSN 2310-9599 (Online) Kemerovo Institute of Editor-in-Chief Food Aleksandr Yu. Prosekov, Dr. Sci. (Eng.), Kemerovo Institute of Food Science and Technology Science and Technology, Kemerovo, Russia FOODS AND Deputy Editor-in-Chief RAW MATERIALS Olga V. Koroleva, Dr. Sci. (Biol.), Bach Institute of Biochemistry, Vol. 2, No. 2, 2014 Moscow, Russia; ISSN 2308-4057 (Print) Zheng Xi-Qun, Dr., Prof., Vice President, Qiqihar University Heilongjiang ISSN 2310-9599 (Online) Province, Qiqihar, P. R. China. Published twice a year. Editorial Board Founder: Gosta Winberg, M.D., Ph.D. Assoc. Prof., Karolinska Institutet, Stockholm, Kemerovo Institute of Food Sweden; Science and Technology Aleksandr N. Avstrievskikh, Dr. Sci. (Eng.), ООО ArtLaif , Tomsk, Russia; (KemIFST), Berdan A. Rskeldiev, Dr. Sci. (Eng.), Shakarim State University, Semei bul’v. Stroitelei 47, Kemerovo, (Semipalatinsk), Kazakhstan; 650056 Russia Aram G. Galstyan, Dr. Sci. (Eng.), All-Russian Research Institute of Dairy Editorial Office, Industry, Moscow, Russia; Publishing Office: Tamara A. Krasnova, Dr. Sci. (Eng.), Kemerovo Institute of Food Science office 1212, bul’v. Stroitelei 47, and Technology, Kemerovo, Russia; Kemerovo, 650056 Russia, Olga A. Neverova, Dr. Sci. (Biol.), Institute of Human Ecology, Siberian phone/fax: +7(3842)39-68-45 Branch, Russian Academy of Sciences, Kemerovo, Russia; http:frm-kemtipp.ru Aleksei M. Osintsev, Dr. Sci. (Eng.), Prof., Kemerovo Institute of Food e-mail: fjournal@mail.ru Science and Technology, Kemerovo, Russia; Printing Office: Viktor A. Panfilov, Dr. Sci. (Eng.), Prof., Moscow State University of Food office 2006, ul. Institutskaya 7, Production, Moscow, Russia; Kemerovo, 650002 Russia, Sergei L. Tikhonov, Dr. Sci. (Eng.), Ural State Academy of Veterinary phone: +7(3842)39-09-81 Medicine, Troitsk, Russia; The Edition is registered by Irina S. Khamagaeva, Dr. Sci. (Eng.), East-Siberian State University of Federal Service for Supervision in Technology and Management, Ulan-Ude, Russia; the Sphere of Telecom, Lidiya V. Shul’gina, Dr. Sci. (Biol.), Pacific Research Fishery Center, Information Technologies and Vladivostok, Russia. Mass Communications Secretary of Editorial Office (Media Registration Certificate Ekaterina V. Dmitrieva, Cand. Sci. (Eng.), Kemerovo Institute of Food PI no. FS77-52352 Science and Technology, Kemerovo, Russia. dated December 28, 2012)
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 CONTENTS FOOD PRODUCTION TECHNOLOGY I. A. Korotkiy Analysis of the Energy Efficiency of the Fast Freezing ofBlackcurrant Berries......... 3 O. V. Kozlova A Study of Properties of Structure-Stabilizing Agents for Products Based on Dairy Raw Materials............................................................................... 15 O. V. Kriger Advantages of Porcine Blood Plasma as a Component of Functional Drinks......... 26 S. M. Lupinskaya Technological Features of the Use of Wild-Growing Raw Materials in the Production of Sour-Milk Beverages................................................................ 32 I S. Milentyeva Research and Development of a Peptide Complex Technology.......................... 40 I A. Smirnova Current Trends in Nonfat Dairy Production..................................................... 47 S. A. Sukhikh Technology of Alcohol Oxidase Production From Yeast Candida Boidinii for Use in Functional Foods Intendedfor Withdrawal Syndrome Alleviation...................... 53 L. V. Tereshchuk Theoretical and Practical Aspects of the Development of a Balanced Lipid Complex of Fat Compositions.................................................................................. 59 L. M. Zakharova Development and Introduction of New Dairy Technologies.............................. 68 BIOTECHNOLOGY O. O. Babich Screening and Identification of Pigmental Yeast Producing L-phenylalanine Opinions of the authors of Ammonia-Lyase and Their Physiological and Biochemical Characteristics............ 75 published materials do not L. S. Dyshlyuk always coincide with the Analysis of the Structural and Mechanical Properties and Micromorphological editorial staff’s viewpoint. Features of Polymeric Films Based on Hydrocolloids of Vegetable Origin Used for Authors are responsible for the the Production of Biodegradable Polymers................................................ 88 scientific content of their papers. Yu. V. Golubtsova The Edition «Foods and Raw The use of Molecular Genetic Markers and PCR for DNA Diagnostics in Raw Materials» is included in the Materials Derived From Fruit and Berries................................................ 98 Russian index of scientific A. Yu. Prosekov citation (RISC) and registered in Theory and Practice of Prion Protein Analysis in Food Products..................... 106 the Scientific electronic library PROCESSES, EQUIPMENT, AND APPARATUSES FOR eLIBRARY.RU THE FOOD INDUSTRY The Journal is included in the I.V. Buaynova International Databases: Simulating the Refrigeration of Batch Dairy Products in a Multizone Cold Supply ResearchBib, EBSCOhost, System...................................................................................................... 121 Ulrich's Periodicals Directory. V. A. Ermolaev Subscription index for the unified Kinetics of the Vacuum Drying of Cheeses.................................................. 130 «Russian Press» catalogue - 41672 S. A. Ivanova Signet for publishing Studing the Foaming of Protein Solutions by Stochastic Methods....................... 140 September 15, 2014 A. M. Osintsev Date of publishing Theoretical and Practical Aspects of the Thermographic Method for Milk September 15, 2014 Coagulation Research................................................................................. 147 Circulation 300 ex. A. M. Popov Open price. Sistemic Regularities in the Study and Design of Technological Complexes for the Kemerovo Institute of Food Production of Instant Peverages.............................................................. 156 Science and Technology STANDARDIZATION, CERTIFICATION, QUALITY, AND SAFETY (KemIFST), bul’v. Stroitelei 47, E. V. Korotkaya Kemerovo, 650056 Russia Biosensors: Design, Classification, and Applications in the Food Industry............ 161 © 2014, KemIFST. INFORMATION All rights reserved. Information for Authors................................................................... 172
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 FOOD PRODUCTION TECHNOLOGY ANALYSIS OF THE ENERGY EFFICIENCY OF THE FAST FREEZING OF BLACKCURRANT BERRIES I. A. Korotkiy Kemerovo Institute of Food Science and Technology, bul'v. Stroitelei 47, Kemerovo, 650056 Russia, phone/fax: +7 (3842) 73-43-44, e-mail: krot69@mail.ru (Received May 5, 2014; Accepted in revised form May 23, 2014) Abstract: In this paper, some results of studying the energy efficiency of the fast freezing of different varieties of blackcurrant berries in a fluidized-bed fast freezer were reported. A method of calculating the energy expenditures on the fast freezing of different varieties of blackcurrant berries in an air fast freezer was proposed. The energy expenditures on the circulation of air at a rate required to create fluidization were determined depending on the air temperature. The energy consumption in the production of artificial cold for the provision of required heat-withdrawing air medium temperatures was calculated. The performed studies were used as a basis to determine the energy-efficient regimes of the low-temperature treatment of blackcurrant berries in an air fast freezer and also the types of a refrigerating machine and a refrigerant, which provided the least energy-consuming fast freezing of blackcurrant berries. Keywords: blackcurrant, fast freezing, energy efficiency of freezing processes UDC 664.8.037.5:634.721 DOI 10.12737/5454 INTRODUCTION The deficit of vitamins and minerals is currently the most widespread and, at the same time, most unwholesome deviation of nutrition from the rational physiologically substantiated standards [1]. Being a natural concentrate of bioactive substances, berries manifest physiologically active properties after entering a human organism and produce an essential effect on its metabolism and vital activity. Blackcurrant is one of the most valuable vitamin-containing plants of the Russian flora. It is rich in ascorbic acid, vitamins B and P. The outstanding value of blackcurrant berries is explained by that vitamins C and P contained in them in great amounts mutually potentiate their health-promoting effects [2]. Freezing is one of the simplest and most widespread methods for the preservation of moisture-containing products. Frozen berries can be stored for many months, as the moisture in them has been brought into a solid state. A decrease in temperature and dewatering during the transition of the moisture contained in berries into a solid state create unfavorable conditions for the development of biochemical reactions in a frozen object, and their rate is abruptly decelerated [3]. The formation of ice crystals alongside with the freezing of a moisture-containing object leads to the destruction of its structure. The destruction of a product’s structure is induced by both mechanical and osmotic factors. Ice crystals formed outside cells deform and destruct their membranes, growing in size during the process of freezing. Moreover, the growth of ice crystals in the intercellular space leads to the diffusion of cellular moisture through membranes and the dewatering of cells. The intensity and character of transformations in a product under freezing depends on the conditions and parameters of the process and the qualitative characteristics of a low-temperature treatment object. The intensification of heat withdrawal in the process of freezing is accompanied by an increase in the amount of crystallization seeds, and this in turn promotes the formation of a microcrystalline structure. The more intense is heat withdrawal, the smaller will be the crystals in a frozen product [4]. In this case, the crystalline structure will be uniform, and ice crystals will form in both the intercellular space and the cells themselves. The withdrawal of heat in the freezing of berries can be intensified either by decreasing the temperature of a heat-withdrawing medium or by accelerating its circulation. In the first case, an increase in heat withdrawal will have an extensive character due to an increase in the temperature difference between a low-temperature treatment object and a heat-withdrawing medium. In the second case, an increase in heat withdrawal will have an intensive character due to an increase in the coefficient of heat transfer between a freezable object and a refrigerating medium [5]. The intensification of heat exchange in the freezing of berries is accompanied by the growth of energy consumption in both the first and second cases. To intensify the heat withdrawal in real berry freezing processes, the cumulative effect of the two above listed factors is used. An important question in the development of a low-temperature treatment technology is the energetic component in the primecost of the finished fresh-frozen fruit and berry products. For this reason, the ratio of the thermal and convective factors is a determinative element in the optimization of energy consumption in 3
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 the low-temperature treatment of berries. The objective of this work was to determine the low-temperature treatment regimes, which would allow the minimization of energy consumption in the production of fast-frozen blackcurrant berries. OBJECTS AND METHODS OF STUDY The fast freezing of berries is performed in fast freezers, which represent devices able to provide a high air circulation rate and required low-temperature treatment temperatures. To determine the critical and optimal parameters of air motion in a freezer, it is necessary to have the data characterizing the mass and volumetric parameters of fruits and berries. Such characteristics of the studied varieties of berries are listed in Table 1. Table 1. Mass and volumetric characteristics of the studied varieties of fruits and berries Variety Product unit Product Bulk density, Bed porosity Product unit mass, g density, kg/m3 kg/m3 diameter, mm Pamyat’ Lisavenko 1.4 1067 741 0.298 13-14 Seyanets Golubki 1.1 1082 751 0.293 12-13 Pamyat’ Shukshina 0.9 1070 743 0.290 11-12 (Olimpiiskaya) Chernyi zhemchug 1.7 1075 746 0.306 14-15 Krasa Altaya 1.1 1059 735 0.295 12-13 Pushistaya 0.8 1063 738 0.291 11-12 The critical air velocities (w'cᵣ, w"cᵣ) are determined in compliance with the following method [6]. The critical air velocity w'cr characterizes the beginning of fluidization. According to the theory of similarity, the heattransfer coefficient can be calculated by the formula [8] а = Nu■ \irK , (5) W ₌ Yar x-------Ar de 1400 + 5.22V Ar ’ (1) where Yair is the air kinematic viscosity, m²/s, and de is the spherical product part’s diameter. The Archimedes number is determined by the formula Ar = g ■ d ■ P e pr Y² ■P air Pair (2) where g = 9.8 m/s² is the gravity acceleration, and Ppr and Pair are the product and air density, respectively. The critical air velocity w''cr is a velocity, at which the entrainment of a product is possible, and where Xₐᵢᵣ is the air heat conductivity, and Nu is the Nusselt number. The Nusselt number for the heat transfer in a fluidized bed can be determined from the empirical equation [9] Nu = 0.03 ■Pr¹/³ ■Re, (6) where Pr = cₚ-pₐᵢᵣ/Xₐᵢᵣ is the Prandtl number, pₐᵢᵣ is the air dynamic viscosity, Pa^s, cₚ is the air specific heat capacity, J/(kg/K), Re = a-depₐᵢᵣ/pₐᵢᵣ, a is the air velocity, m/s, and Pair is the air density, kg/m³. The air amount mair (kg) required to freeze a kilogram of berries is determined by the formula air Д h cp -Дtair (7) cr Y Ar = -rsx x------=. de 18 + 0.6V Ar (3) To determine the freezing time for moisturecontaining food products, the Planck formula is most widely used [7]: where Ah is the difference between the enthalpies of berries before and after freezing (at 10 and -18°С, J/kg), and Atair is the air heating, K. The air heating in the freezing of berries is found as Д t . = а ■ F ■ Д t , (8) air pr m qfr 'P pr x df ( -%- + -t -1 ■ 6 4 Л f а crryo a air у fc У (4) where а is the product-to-air heat-transfer coefficient, W/(m²/K), fyᵣ is the heat conductivity of the product’s frozen part, W/(m/K), pₚᵣ is the product density, kg/m³, qjr is the specific heat withdrawn from a product in the process of freezing, J/kg, tcryo is the cryoscopic temperature, °C, and tₐᵢᵣ is the air temperature. The heat-transfer coefficient is determined depending on the velocity and regime of the air flow, its thermodynamic parameters, and the shape and size of a product. where Fpr is the surface area of berries, m², and Atm is the logarithmic mean temperature difference between the air and freezable berries. In turn, Atm can be calculated as t „ — t . air 2 ¹ air 1 t — t ■ ln cryo air 1 tt cryo air2 (9) where tcryo is the cryoscopic temperature of berries, tair1 is the initial air temperature, tair2 is the final air temperature, and Ataiᵣ = tair2 - tari. m w 4
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 Since the initial air temperature (tair1) is specified, the final air temperature (tair2) can be determined by Eq. (9). The air volume required to freeze a kilogram of berries is calculated as Vair mair/Pair . ⁽¹⁰⁾ The energy (Lfan), which should be spent on the circulation of this air volume at a required rate can be found as Lfan = Vair'AP/f, (11) where f is the fan efficiency coefficient, which is nearly Ufan = 0.76 for centrifugal fans operating under the conditions of a fast freezer, AP is the aerodynamic resistance to the motion of air in the circuit of a fast freezer. The aerodynamic losses during the motion of air in a fast freezer occur in the fluidized bed, the supporting grid, the finned air cooler sections, upon the turns of the air flow at the fan’s inlet, and in the fan’s diffuser. The greatest aerodynamic losses take place in the fluidized bed, the supporting grid, and the air cooler sections. The other listed regions of the air circuit structurally belong to the fan, and the aerodynamic losses in them are small in comparison with the other regions, so they may be included into the fan efficiency coefficient instead of being taken into consideration in particular calculations. The aerodynamic resistance of the fluidized bed (APfl, Pa) can be determined by the following method [6]: A P ₙ = 1.6 7 f Re Hfl- ¹ x Gpr- , ⁽¹²⁾ I de ) Fpr where Hfl is the fluidized product bed height, Gpr is the product mass, and Fpr is the surface area occupied by a product on the grid, m². f H 0 f T^ 1 • <¹³) к 1 - s ) where s₀ is the bulk bed porosity (Table 1), f 18Re+ 0.36 Re² Y'2¹ s = I--------------I is the fluidized bed porosity, к Ar ) and H0 is the bulk product bed height, m. The aerodynamic resistance of the supporting grid with meshes of 3 x 3 mm in size and the free air flow area E = 0.308 (APg, Pa) is APg = 13.72-w ² - 43.12-w + 119.36, (14) where w is the air flow velocity, m/s. The aerodynamic resistance of the finned air cooler section (APac, Pa) is found from the dependence APac = 1.35-А-Re⁻⁰.²⁴ pₘr - w², (15) where А is the coefficient taking into account the structural features of the air cooler. Hence, the aerodynamic resistance to the air flow in the circulation circuit of the air cooler (AP, Pa) can be found from the equation AP = (APfi + APg + APac)a, (16) where a = 1.1 is the coefficient taking into account the friction resistances to the air flow. The working fluid in the cycles of refrigerating machines participates in different thermodynamic processes. The efficiency of refrigerating machines depends on the fashion, in which these processes are performed. The problem of thermodynamic analysis based on the first and second laws of thermodynamics is to ascertain the possible efficiency of refrigerating machine cycles [10]. The refrigeration efficiency of one-stage, two-stage, and cascade refrigerating machines operating on freons R-134a, R-22, R-404a, R-23, and ammonia was studied. The energy expenditures on the production of artificial cold were estimated by the method described in [11]. The ambient medium is of great importance in the thermodynamic theory of refrigerating machines. The ambient medium is first of all characterized by the independence of its parameters on the operation of a considered refrigerating machine. This means that any action of a refrigerating machine produces no changes in the ambient medium. The atmospheric air with a temperature from 15 to 35°C was considered as such a medium. An important condition for the implementation of a refrigeration engineering solution is the organization of heat exchange between a working fluid and the ambient medium, and also a cold-carrying agent, which performs the transfer of heat from a freezable object to a working fluid without appreciable expenditures. To perform the thermal analysis of the efficiency of refrigeration cycles, the temperature difference between a working fluid and the ambient medium in the evaporator was taken equal to 10°C, and the temperature difference between a working fluid and the air leaving the air cooler was also set equal to 10°C. The working cycle of a one-stage compression refrigerating machine is shown in Fig. 1a in the p-i (pressure-enthalpy) coordinates. In this cycle, 1 -2 is compression in the compressor, 2-3' is cooling of a cooling agent and condensation in the condenser, and 3'-3 and a-1 are heat regeneration in the recuperative heat exchanger of freon refrigerating machines. Heat regeneration in ammonia refrigerating machines is unreasonable. Process 3-4 is expansion in an expanding device. Process 4-a is boiling of a cooling agent in the evaporator. The overheating of a working fluid before the compressor is estimated by the formula AToh = T1 - Tₐ. For ammonia refrigerating machines, the overheating of a working fluid at suction onto the compressor is taken to be AToh = 5-10°C. Let us set AToh = 10°C. For freon refrigerating machines, AToh = 15-35°C. Let us set AToh = 30°C. The overcooling before expansion is calculated as follows. For regeneration cycle refrigerating machines, it is determined from the energy balance of a recuperative heat exchanger hLⁱⁿ - hLout= hVout - hVⁱⁿ. (17) 5
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 For non-regeneration cycle (ammonia) refrigerating machines, the temperature of the liquid cooling agent before the expanding valve is taken to be 1-3 °C lower than the temperature of the liquid leaving the condenser (tc), i.e., tL = tc - (1-3°C). The specific refrigeration capacity of a refrigerating machine q0, the specific adiabatic compression work in the compressor ls, and the real mass and volumetric capacities of the compressor Greal and Vreal are then determined. The specific refrigeration capacity of a refrigerating machine will be q0=ha - h4 . (18) The specific adiabatic work of the compressor is determined from the formula lad = h2 - h1 . (19) The power of a refrigerating machine Ne (kW), which should be provided to withdraw a certain amount of heat per unit time Q0 (kW) from a freezable object is determined by the following method: Ne = Ni + Nfr , (20) where Ni is the indicated power of the compression of a working fluid in the compressor, and Nfr is the power spent on friction and the driver of auxiliary devices, N = Greal lad, (21) where Gi is the mass flow rate of a cooling agent circulating in a refrigerating machine (kg/s), and ц, is the indicated efficiency coefficient of the compressor. The friction power is determined from the empirical formula Nfr = pi,frVt , (22) where pifr = (40-90)403 Pa is the friction pressure, and Vt is the theoretical volumetric capacity of the compressor (m³/s). The mass flow rate of a cooling agent is determined as Greal = Q0/q0. (23) The theoretical volumetric capacity is found by the formula Vt=Greal V1Я (24) where v1 is the specific volume of a working fluid sucked into the compressor, Я the delivery coefficient of the compressor, Я = f(pfrcd/psuct). Here pfrcd is the pressure, to which a working fluid is compressed immediately in the working members of the compressor, and psuct is the pressure of the working fluid entering immediately into the working space of the compressor. The method of the estimation of Я is described in [11]. A vapor-compression refrigerating machine can be implemented in different designs. We have considered a refrigerating machine in the simplest and, consequently, most acceptable implementation for the supply of a self-contained fast freezer with cold. The working cycle of a two-stage compression single-expansion refrigerating machine is shown in Fig. 1b in the p-i coordinates. In this cycle, 1-2a is compression in the compressor of stage I, 2a-1a is cooling in the interstage cooler due to the transfer of compression heat to the ambient medium, 2-3' is compression in the compressor of stage II and cooling of a cooling agent and condensation in the condenser, and 3 '-3 and a-1 are regeneration of heat in the recuperative heat exchanger of freon refrigerating machines. In ammonia refrigerating machines, t3 = t3’- (1-3°C). Process 3-4 is expansion in the expanding device. Process 4-a is boiling of the cooling agent in the evaporator. (a) (b) Fig. 1. Theoretical cycle of a refrigerating machine in the p-h (pressure-enthalpy) coordinates: (a) one-stage compression cycle, (b) two-stage compression cycle. The method of calculating the cycle of a two-stage compression refrigerating machine principally corresponds to the method of calculating the cycle of a one-stage compression refrigerating machine, but has some peculiarities. The interstage pressure is selected by the formula Plnt = л/Р 1P 2 , ⁽²⁵⁾ or from the condition of the maximally admissible compression end temperature for a studied cooling agent. The temperature of point 1a is determined from the ambient temperature and the condition of the 6
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 undercooling of a cooling agent in the interstage cooler due to heat underrecuperation. The two-stage compression work is determined by the formula Icomp = ll + llI=(h2a — hl) + (h₂ — hla) . (26) In cascade refrigerating machines, at least two working fluids are used. A two-cascade refrigerating machine consists of two independent refrigeration cycles called branches. The interaction between the branches of a cascade refrigerating machine occurs in heat exchangers. In the lower low-temperature branch, a high-pressure working fluid is used (we used freon R-23 with a normal boiling temperature of -82.14°C). The cooling agent of the upper branch was freon R-22 with a normal boiling temperature of -40.81°C. The upper branch of a cascade refrigerating machine is designed for the withdrawal of condensation heat from the cooling agent of the lower branch and its transfer to the ambient medium. The working cycle of a cascade refrigerating machine is shown in Fig. 2. (a) (b) Fig. 2. Theoretical cycle of a two-cascade refrigerating machine: (a) upper (high-temperature) cascade branch, (b) lower (low-temperature) cascade branch. Here, ilmw-2lmw is compression in the compressor of the lower cascade branch, 2Imw-2Imwa is cooling of a cooling agent in the heat exchanger due to the withdrawal of heat into the ambient medium, 2Imwb-3Imw' is condensation of the cooling agent of the lower cascade branch in the evaporative condenser due to the withdrawal of condensation heat by the upper cascade branch, 3lmw'- 3lmw is overcooling of the liquid cooling agent of the lower branch in the regenerative heat exchanger due to heat exchange with the cooling agent sucked into the compressor (Olow—llow), 3°ow__4°ow is expansion in the expanding device, 4oo'-4o⁰' is boiling in the evaporator of the lower branch. The upper cascade branch works by the cycle similar to the cycle of a one-stage compression refrigerating machine, but process 4up-aup is boiling of the cooling agent of the upper cascade branch in the evaporative condenser due to the delivery of heat from the condensing cooling agent of the lower cascade branch. The temperature difference between the cooling agents of the branches due to underrecuperation is 3-5°C. The refrigerating capacity of a cascade refrigerating machine is controlled by the refrigerating capacity of the lower cascade branch, and the work expenditures correspond to the total work expenditures in both cascades. When determining the work expenditures on the freezing of fruits and berries, it was necessary not only to take into account the work expenditures on the withdrawal of crystallization heat from a product and the heat spent on the cooling of fruits and berries before and after crystallization. It was also necessary to take into consideration the heat inflow through the heat-insulating enclosures of a freezer Ql and the heat inflow from the air entering a freezer through the charge and discharge ports Q4. The heat inflow Ql is determined by the formula Qi = ДkFi)At , (27) where k is the heat-transfer coefficient of heatinsulating enclosures and depends on the type and thickness of heat insulation, the averaged value k = 0.21 W/(m² k) is taken in our calculations; F is the surface area of heat-insulating enclosures and depends on the dimensions and shape of a freezer, and At is the temperature difference between the ambient air and the air in a fast freezer. Since the surface area of heat-insulating enclosures can not be taken into account without the knowledge of the real dimensions of a fast freezer, the parameter Д kiFi) was replaced by the specific heat flux through the enclosures per unit mass of a freezable product ql. This parameter was taken to be ql = 90 W/(kg K) from averaged values. The heat inflow from the air entering and leaving a freezer through the charge and discharge ports was taken from the recommendations Q4 = 0.4Ql. RESULTS AND DISCUSSION The experimental data given in Table 1 and Eqs. (1)-(3) were used to obtain the critical velocities of the studied fruit varieties. The results of calculations are plotted in Fig. 3. From the performed calculations for the studied varieties of berries and fruits, it follows that the range of velocities, at which the phenomenon of fluidization takes place (from the appearance of a fluidized bed to the velocity, at which the entrainment of fruits and berries is possible), is 1.24-17.7 m/s at temperatures from -43 to -13°C for all the studied varieties. Since every variety of fruits and berries has its own range of air velocities, at which the process of fluidization is stable, we have used for studies the range of velocities, at which the process of fluidization without the entrainment of fruits and berries is ensured for all the studied varieties. These air velocities were from 2 to 11.5 m/s. Using Eqs. (4)-(6), the freezing time was calculated for the studied varieties of blackcurrant berries at different air velocities and temperatures, and the results of calculations were plotted in Fig. 4. 7
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 (a) (b) Fig. 3. Critical fluidization velocities of blackcurrant berries versus temperature: (1) Chernyi zhemchug, (2) Pamyat’ Lisavenko, (3) Seyanets Golubki, (4) Krasa Altaya, (5) Pamyat’ Shukshina, (6) Pushistaya, (a) fluidization beginning velocity, (b) berry entrainment velocity. E T emperature, °C Pamyat’ Shukshina T emperature, °C Chernyi zhemchug 10 m/s 14 m/s ,g Fig. 4. Freezing time versus temperature for the freezing of the studied varieties of blackcurrant berries from the initial temperature of 10°C to the temperature of -18°C in a fluidized-bed fast freezer at different air velocities. 8
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 Using Eqs. (7)-(16), the energy expenditures on the circulation of air in a fast freezer were calculated depending on the air temperature and velocity. The energy expenditures were calculated for the freezing of blackcurrant berries from the initial temperature tinit = 10°C to the temperature tfin = -18°C. The results of calculations are plotted in Fig. 5. Fig. 5. Energy expenditures (kJ/kg) on the circulation of air in a fast freezer depending on the air velocity and temperature for the freezing of a kilogram of blackcurrant berries of studied varieties from the initial temperature of 10°C to the temperature of -18°C. The results of calculations indicate the existence of a certain range of air velocities, at which the air circulation energy expenditures are minimal at a certain freezing air temperature for the studied varieties of blackcurrant berries. Thus, the optimal range of velocities for blackcurrant berries is 6-7 m/s. An increase in the velocity of air passing through the bed of berries intensify the transfer of heat from freezable fruits and decreases the freezing time, so a smaller circulating air amount is required for the freezing of berries. However, the aerodynamic losses grow proportionally to the squared air velocity. Hence, an increase in the air velocity decreases the required air flow rate for the withdrawal of heat in the process of freezing and, consequently, the energy expenditures on the transport of a necessary air amount. At the same time, an increase in the air velocity leads to the growth of energy expenditures due to the need to overcome aerodynamic resistances. Hence, at the initial stage, a decrease in energy expenditures due to a reduction in the amount of circulating air compensates an increase in the energy spent to overcome aerodynamic resistances. When the air velocity attains the values exceeding the optimal level, the growth of the energy expenditures required to overcome aerodynamic resistances become quicker than a decrease in the 9
ISSN 2308-4057. Foods and Raw Materials Vol. 2, No. 2, 2014 energy expenditure due to a reduction in the required amount of circulating air, so the total energy expenditures on the circulation of air grow. The calculated required specific refrigeration capacity of a refrigerating machine for the freezing of a kilogram of blackcurrant berries as a function on the air temperature in a fast freezer and the ambient air temperature is plotted in Fig. 6. Fig. 6. Required refrigeration capacity (kJ/kg) of a refrigerating machine for the freezing of a kilogram of blackcurrant berries from the temperature of 10°C to the temperature of -18°C depending on the air temperature in a fast freezer and the ambient air temperature. The calculation results plotted in Fig. 6 for the required refrigeration capacity of a refrigerating machine depending on the ambient medium temperature and the air temperature in a freezer indicate that the required refrigeration capacity of a refrigerating machine for the freezing of different varieties of the same species of berries and fruits differs slightly. The required refrigeration capacity of a refrigerating machine for the freezing of a kilogram of blackcur rant berries differs by less than 1.9% depending on their variety. The comparative analysis of the energy efficiency of different refrigeration schemes used for the freezing of fruits and berries was performed using Pamyat’ Lisavenko blackcurrant berries. The results of the comparative calculations of the energy expenditures on the freezing of berries in one-stage refrigerating machines are shown in Fig. 7. 10